Technical Ceramics Group

Protective coatings and multifunctional ceramic composites containing carbon nanostructures

Definition and objetives

 

Our current objectives are focussed in three areas:

The activities of the group relate with ceramic materials working under stringent conditions of diverse kind, such as high loads, high temperatures, corrosive atmospheres, friction and wearing conditions. These events are common in many technological systems as gas turbines and engines, spatial vehicles, fusion reactors, etc. Miniaturization of components envisaged for applications in MEMS is also a target of our research.

The group has wide expertise in the following techniques/methods: Spark plasma sintering, Thermal diffusivity/conductivity, Wear and friction tests, Fracture and strength testing, Depth sensing (micro/nano) indentation methods, Robocasting, Thermal spraying.




  • Protective coatings for high temperature systems, such as environmental barrier coatings (EBC) and self-healing thermal shields. Our activities comprise: powder engineering technology, coating deposition by flame spraying and ageing tests. Besides the main protective function, these coatings should be able to sustain mechanical and thermal loads without failing. 

  • Development of multifunctional ceramic composites containing carbon nanostructures, namely carbon nanotubes (CNT), graphene multistacks and graphene oxide (GO). Enhancement on toughness, strength or wear/friction resistance in conjunction with an added electrical conductivity or an increased thermal conductivity, induced by the carbon based nano-filler, are the aims of this research. Targeted applications are engine and turbine components, MEMS, sliding parts, etc.




  • Cellular ceramics, i.e. complex structures with high porosity and 3D assemblies using methods such as polymeric sponge replica and robocasting. A extensive range of applications, such as gas burners, catalytic supports, filters, heat sinks and exchangers, are feasible.

NEWS

Drs Belmonte, Miranzo and Osendi gave corresponding talks in the Admat wokshop organized by the  Institute of Therm mechanics, ASCR, in Prague.


Cristina Ramirez will defend her PhD research work Materiales multifuncionales de Si3N4 con nanoestructuras reforzantes basadas en grafeno” on June 16th, at 12:00 in the ICV General Hall.


Article usage dashboard:

Extraordinary toughening enhancement and flexural strength in Si"3N"4 composites using graphene sheets.


29-30 October: Dr. Hanus Seiner and Dr. Petr Sedlak, from the Institute of Thermomechanics (Prague, Czech Republic), visited us as part of the collaboration between our respective groups. Dr. Seiner and Dr. Sedlak are specialized in the determination of elastic constants and internal friction coefficients of advanced materials using the Resonant Ultrasound Spectroscopy (RUS).




July 2013: Dr. M. Belmonte will stay for 3 months in Prof. Terrones’ group at Research Center for Exotic Nano Carbons, Shinshu University (Japan) to develop hybrid graphene-ceramic materials for tribological and multifunctional applications


April 2013: New publication, Synthesis of conducting graphene/Si3N4 composites by spark plasma sintering. Carbon, 57 425–432 (2013)DOI.


October 2012: New patent, Procedure for obtainig ceramic granulated feedstock for thermal spraying apllications.